Synthesis and characterisation of MIL-101(Cr) using different additives
DOI:
https://doi.org/10.24191/mjcet.v6i1.21824Keywords:
MIL-101 (Cr), Metal-organic framework, CO2 adsorptionAbstract
MIL-101(Cr), a subgroup of metal-organic framework that has the capabilities as an adsorbent for CO2 removal because of its large pore volume and high surface area. It is now commonly used to remove CO2 from raw natural gas components as well as capture or lower CO2 from flue gas or the atmosphere. The presence of CO2 in raw natural gas will corrode the pipelines and lower the heating value which will lead to an increase in transportation costs. Therefore, it is significant to study the synthesis of MIL-101(Cr) with improved properties. Generally, the morphology and properties improvement of MIL-101(Cr) can be modified by the addition of additives or modulators (i.e., NaOH, HNO3, HF). Hence, the objectives of this study are to synthesise the metal-organic framework of MIL-101(Cr) with different additives, and to characterise and analyse the synthesised MIL-101(Cr). The effect of adding modulators (additives) to MIL-101(Cr) was systematically discussed through X-Ray Diffraction (XRD), Scanning Electron Microscope (SEM), and Fourier Transform Infrared Spectroscopy (FTIR) analysis. The results showed that the Cr component was successfully integrated into each sample and MIL-101(Cr) – Non has a small particle size which indicates a larger surface area thus reflecting high porosity. It also has unsaturated metal sites which makes it excellent properties for gas adsorption.
References
Bayazit, Ş. S., Danalıoğlu, S. T., Abdel Salam, M., & Kerkez Kuyumcu, Ö. (2017). Preparation of magnetic MIL-101 (Cr) for efficient removal of ciprofloxacin. Environmental Science and Pollution Research, 24(32), 25452–25461. https://doi.org/10.1007/s11356-017-0121-0
Chen, C., Feng, N., Guo, Q., Li, Z., Li, X., Ding, J., Wang, L., Wan, H., & Guan, G. (2018). Template-directed fabrication of MIL-101(Cr)/mesoporous silica composite : Layer – packed structure and enhanced
performance for CO2 capture. Journal of Colloid and Interface Science, 513, 891–902. https://doi.org/10.1016/j.jcis.2017.12.014
Chong, K. C., Ho, P. S., Lai, S. O., Lee, S. S., Lau, W.J., Lu, S. Y., & Ooi, B. S. (2022). Solvent-Free Synthesis of MIL-101(Cr) for CO2 Gas Adsorption: The Effect of Metal Precursor and Molar Ratio. Sustainability (Switzerland), 14(3), 1–12. https://doi.org/10.3390/su14031152
He, C., Liu, D., & Lin, W. (2015). Nanomedicine Applications of Hybrid Nanomaterials Built from Metal-Ligand Coordination Bonds: Nanoscale Metal-Organic Frameworks and Nanoscale Coordination Polymers. Chemical Reviews, 115(19), 11079–11108. https://doi.org/10.1021/acs.chemrev.5b00125
Hong, D. Y., Hwang, Y. K., Serre, C., Férey, G., & Chang, J. S. (2009). Porous chromium terephthalate MIL-101 with coordinatively unsaturated sites: Surface functionalization, encapsulation, sorption, and catalysis. Advanced Functional Materials, 19(10), 1537–1552. https://doi.org/10.1002/adfm.200801130
Kamal, K., Bustam, M. A., Ismail, M., Grekov, D., Shariff, A. M., & Pré, P. (2020). Optimization of washing processes in solvothermal synthesis of nickel-based mof-74. Materials, 13(12), 1–10. https://doi.org/10.3390/ma13122741
Lin, R. B., Xiang, S., Xing, H., Zhou, W., & Chen, B. (2019). Exploration of porous metal–organic frameworks for gas separation and purification. Coordination Chemistry Reviews, 378, 87–103. https://doi.org/10.1016/j.ccr.2017.09.027
Liu, Q., Ning, L., Zheng, S., Tao, M., Shi, Y., & He, Y. (2013). Adsorption of Carbon Dioxide by MIL- 101(Cr): Regeneration conditions and influence of flue gas contaminants. Scientific Reports, 3, 1–6. https://doi.org/10.1038/srep02916
Rajati, H., Navarchian, A. H., & Tangestaninejad, S. (2018). Preparation and characterization of mixed matrix membranes based on Matrimid/PVDF blend and MIL-101(Cr) as filler for CO2/CH4 separation. Chemical Engineering Science, 185, 92–104. https://doi.org/10.1016/j.ces.2018.04.006
Sheikh Alivand, M., Hossein Tehrani, N. H. M., Shafiei-Alavijeh, M., Rashidi, A., Kooti, M., Pourreza, A., & Fakhraie, S. (2019). Synthesis of a modified HF-free MIL-101(Cr) nano adsorbent with enhanced H2S/CH4 , CO2 /CH4, and CO2 /N2 selectivity. Journal of Environmental Chemical Engineering, 7(2), 102946. https://doi.org/10.1016/j.jece.2019.102946
Taufiq Musa, M., Shaari, N., & Kamarudin, S. K. (2021). Carbon nanotube, graphene oxide and montmorillonite as conductive fillers in polymer electrolyte membrane for fuel cell: an overview. International Journal of Energy Research, 45(2), 1309–1346. https://doi.org/10.1002/er.5874
Wang, H., Lustig, W. P., & Li, J. (2018). Sensing and capture of toxic and hazardous gases and vapors by metal-organic frameworks. Chemical Society Reviews, 47(13),4729–4756. https://doi.org/10.1039/c7cs00885f
Yulia, F., Nasruddin, Zulys, A., & Ruliandini, R. (2019). Metal-organic framework-based chromium terephthalate (MIL-101 Cr) growth for carbon dioxide capture: A review. Journal of Advanced Research in Fluid Mechanics and Thermal Sciences, 57(2), 158–174.
Zhang, L. J., Li, F. Q., Ren, J. X., Ma, L. B., & Li, M. Q. (2018). Preparation of metal organic frameworks MIL-101 (Cr) with acetic acid as mineralizer. IOP Conference Series: Earth and Environmental Science, 199(4). https://doi.org/10.1088/1755-1315/199/4/042038
Zhao, M., Yuan, K., Wang, Y., Li, G., Guo, J., Gu, L., Hu, W., Zhao, H., & Tang, Z. (2016). Metal- organic frameworks as selectivity regulators for hydrogenation reactions. Nature, 539(7627), 76–80. https://doi.org/10.1038/nature19763
Zhao, T., Li, S. H., Shen, L., Wang, Y., & Yang, X. Y. (2018). The sized controlled synthesis of MIL- 101(Cr) with enhanced CO2 adsorption property. Inorganic Chemistry Communications, 96, 47–51. https://doi.org/10.1016/j.inoche.2018.07.036
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