Removal of fluoride and ammoniacal nitrogen from fertilizer wastewater industry using acetylene production sludge (APS)

Authors

  • Nur Ain Mohd Zainuddin Integrated Separation Technology Research Group (i-STRonG), School of Chemical Engineering, College of Engineering, Universiti Teknologi MARA, 40450 Shah Alam, Selangor, Malaysia
  • Rohaiyati Md Rodzay Integrated Separation Technology Research Group (i-STRonG), School of Chemical Engineering, College of Engineering, Universiti Teknologi MARA, 40450 Shah Alam, Selangor, Malaysia
  • Kamariah Noor Ismail Integrated Separation Technology Research Group (i-STRonG), School of Chemical Engineering, College of Engineering, Universiti Teknologi MARA, 40450 Shah Alam, Selangor, Malaysia
  • Siti Wahidah Puasa Integrated Separation Technology Research Group (i-STRonG), School of Chemical Engineering, College of Engineering, Universiti Teknologi MARA, 40450 Shah Alam, Selangor, Malaysia

DOI:

https://doi.org/10.24191/mjcet.v5i1.15015

Keywords:

Fluoride removal, Ammoniacal Nitrogen removal, Fertiliser wastewater, Precipitation, Acetylene Production Sludge (APS)

Abstract

Wastewater from the fertiliser industry has caused a major problem to the inland water due to the high contaminant of fluoride and ammoniacal nitrogen (AN). Acetylene production sludge (APS) was chosen in this study due to its efficiency. Its properties can aid the wastewater treatment process and it is also environmentally friendly. The characteristics of APS were anaysed by using X-ray diffraction (XRD) and X-ray fluorescent (XRF). This investigation was not only for fluoride and AN removal, but also on chemical oxygen demand (COD) of the wastewater. Jar test was conducted, on the percentage removal of fluoride and AN by varying the parameter such as pH and APS dosage. Fluoride and AN were found to be reduced at an optimum APS dosage of 2.0 g with a pH of 10.18. Meanwhile COD was reduced at an optimum APS dosage of 2.5 g with a pH of 11.38. The maximum percentage removal of fluoride, AN and COD were 15.02%, 51.84%, and 6.64% respectively. The APS performance was then validated by multilinear regression using Excel Data Analysis ToolPak based on the experimental data obtained. The study shows that APS is a waste material that has a potential to be repurposed for treating fluoride and AN contaminated wastewater. 

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Published

2022-04-30

How to Cite

Mohd Zainuddin, N. A., Md Rodzay, R., Ismail, K. N., & Puasa, S. W. (2022). Removal of fluoride and ammoniacal nitrogen from fertilizer wastewater industry using acetylene production sludge (APS). Malaysian Journal of Chemical Engineering &Amp; Technology, 5(1), 29–37. https://doi.org/10.24191/mjcet.v5i1.15015