Physico-mechanical and water absorption properties of LDPE/cassava starch film
DOI:
https://doi.org/10.24191/mjcet.v4i2.13825Keywords:
Degradable plastic, Tapioca starch, Low-density polyethylene, Water absorption, Plant polybagAbstract
Plastic waste is a global crisis, and Malaysia is the 8th worst country worldwide for plastic waste. With this trend, growing market demands for green product have imposed pressure on industries to find an alternative to petroleum-based plastic. Degradable plastic is introduced to overcome this limitation. The present work investigates degradable plastic film of low-density polyethylene incorporated with cassava starch (LDPE-CS). The compounding of the LDPE-CS was prepared via pre-mixing, blending, resin crushing, and film hot pressing. Film thickness, tensile strength, elongation, water absorption, and field test were conducted on the LDPE-CS and commercial LDPE (control). Experimental data of LDPE-CS and commercial LDPE films were evaluated and compared. Thickness of LDPE-CS film was 0.18 mm which was 51% thicker than the control film. Tensile strength and elongation of the LDPE-CS were 7.04 MPa and 5.39%, while control film was 12.77 MPa and 921.5%, respectively. The tensile strength and elongation of the LDPE-SC were significantly lower than the control film, which may be due to the weak interface between LDPE and starch. The water absorption test revealed that the LDPE-CS film absorbed water by 4.8%, which indicates its degradability in the water. The field test shows that the LDPE-CS is biodegradable and comparable with the commercial plant polybag in terms of its capability in planting.
References
Ahamed, N. T., Singhal, R. S., Kulkarni, P. R., Kale, D. D., & Pal, M. (1996). Studies on Chenopodium quinoa and Amaranthus paniculatas starch as biodegradable fillers in LDPE films. Carbohydrate Polymers, 31(3), 157–160. https://doi.org/10.1016/S0144-8617(96)00019-7
ASTM D882-10, Standard Test Methods for Tensile Properties of Thin Plastic Sheeting, ASTM International, PA, 2010, https://doi.org/10.1520/D0882-10.2
Datta, D., & Halder, G. (2018). Enhancing degradability of plastic waste by dispersing starch into low density polyethylene matrix. Process Safety and Environmental Protection, 114, 143–152. https://doi.org/10.1016/j.psep.2017.12.017
Garg, S., & Jana, A. K. (2007). Studies on the properties and characteristics of starch-LDPE blend films using cross-linked, glycerol modified, cross-linked and glycerol modified starch. European Polymer Journal, 43(9), 3976–3987. https://doi.org/10.1016/j.eurpolymj.2007.06.030
Kormin, S., Kormin, F., & Dalour Hossen Beg, M. (2018). Study of natural weathering exposure on properties of ldpe incorporated with sago starch. Materials Today: Proceedings, 5(10), 21636–21643. https://doi.org/10.1016/j.matpr.2018.07.013
Mao, D., Vi, T., Do, V., Grillet, A., & Ha, H. (2016). International Biodeterioration & Biodegradation Biodegradability of polymer film based on low density polyethylene and cassava starch. International Biodeterioration & Biodegradation, 115, 257–265. https://doi.org/10.1016/j.ibiod.2016.09.004
Marichelvam, M. K., Jawaid, M., & Asim, M. (2019). Corn and rice starch-based bio-plastics as alternative packaging materials. Fibers, 7(4), 1–14. https://doi.org/10.3390/fib7040032
Nguyen, D. M., Do, T. V. V., Grillet, A. C., Ha Thuc, H., & Ha Thuc, C. N. (2016). Biodegradability of polymer film based on low density polyethylene and cassava starch. International Biodeterioration and Biodegradation, 115, 257–265. https://doi.org/10.1016/j.ibiod.2016.09.004
Ojogbo, E., Ogunsona, E. O., & Mekonnen, T. H. (2020). Chemical and physical modifications of starch for renewable polymeric materials. Materials Today Sustainability, 7–8, 100028. https://doi.org/10.1016/j.mtsust.2019.100028
Prachayawarakorn, J., & Pomdage, W. (2014). Effect of carrageenan on properties of biodegradable thermoplastic cassava starch/low-density polyethylene composites reinforced by cotton fibers. Materials and Design, 61, 264–269. https://doi.org/10.1016/j.matdes.2014.04.051
Pushpadass, H. A., Bhandari, P., & Hanna, M. A. (2010). Effects of LDPE and glycerol contents and compounding on the microstructure and properties of starch composite films. Carbohydrate Polymers, 82(4), 1082–1089. https://doi.org/10.1016/j.carbpol.2010.06.032
Wahyuningtyas, N., & Suryanto, H. (2017). Analysis of Biodegradation of Bioplastics Made of Cassava Starch. Journal of Mechanical Engineering Science and Technology, 1(1), 24–31. https://doi.org/10.17977/um016v1i12017p024
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