Effect of different loading low density polyethylene (LDPE) on the thermal and mechanical properties of Tapioca starch-based plastic composite

Authors

  • Norin Zamiah Kassim Shaari Faculty of Chemical Engineering, Universiti Teknologi MARA, Selangor, Malaysia
  • Mazlan Bairik Faculty of Chemical Engineering, Universiti Teknologi MARA, Selangor, Malaysia
  • Junaidah Jai Faculty of Chemical Engineering, Universiti Teknologi MARA, Selangor, Malaysia

DOI:

https://doi.org/10.24191/mjcet.v3i1.10928

Keywords:

Composite, Tapioca starch, LDPE, Glycerol, Citric acid

Abstract

Effect of incorporating different loading of low densities polyethylene (LDPE) on the mechanical and thermal properties of the plastic composite made from tapioca starch was investigated. The compound formulation was done in the internal mixer and the lump produced was crushed. Then, the crushed sample was compressed to form a dumbbell-shaped in a compression molding equipment, heated at 140oC. The sample was subsequently analyzed for tensile property, thermal stability and functional groups. Results show that the incorporation of LDPE improves thermal and mechanical stabilities of the plastic composite. However, too much LDPE causes lower ductility of the composites. LDPE-15 was found as the best formulation since it has moderate tensile strength with good elongation.

References

A.A. Shah, F. Hasan, A. Hameed, S. Ahmed, (2008). Biological Degradation of Plastics: A Comprehensive Review. Biotechnology Advances. 26. 246–265. https://doi.org/10.1016/j.biotechadv.2007.12.005

A.P. Bilck, C. Maria, O. Müller, J.B. Olivato, M. Victoria, E. Grossmann, F. Yamashita, (2015). Using Glycerol Produced from Biodiesel as A Plasticiser in Extruded Biodegradable Films. Polimeros. 25(4). 331–335. doi: 10.1016/j.foodchem.2009.05.050

H.A. Pushpadass, P. Bhandari, M.A. Hanna, (2010). Effects of LDPE and Glycerol Contents and Compounding on The Microstructure and Properties of Starch Composite Films. Carbohydrate Polymers. 82. 1082–1089.

http://dx.doi.org/10.1016/j.carbpol.2015.10.093

J. Yu, N. Wang, X. Ma, (2005). The Effects of Citric Acid on The Properties of Thermoplastic Starch Plasticized by Glycerol. Starch-Stärke 2005. 57. 494–504.

J.F. Mendes, R.T. Paschoalin, V.B. Carmona, A.R. Sena Neto, A.C.P. Marques, J.M. Marconcini, L.H.C. Mattoso, E.S. Medeiros, J.E. Oliveira, (2015). Biodegradable Polymer Blends Based on Cornstarch and Thermoplastic Chitosan Processed by Extrusion. Carbohydrate Polymers. 1–19.

M. Mahl, C. Jelich, H. Baier, (2017). Thermo-mechanical Behavior of Polyethylene Under Mechanical Loads at Cryogenic and Elevated Temperatures. International Journal of Pressure Vessels and Piping. 150. 11–18.

M.Z.B. Yunos, W.A.W.A. Rahman, (2011). Effect of Glycerol on Performance Rice Straw/Starch Based Polymer. Journal of Applied Sciences. 11. 2456–2459.

N. Reddy, Y. Yang, (2010). Citric Acid Cross-Linking of Starch Films. Food Chemistry. 118. 702–711. N.H. Yusof, N. Rahman, S.Z. Sulaiman, A.H. Sofian, M.S.Z. Mat Desa, I. Izirwan, (2018). Development of Low-Density Polyethylene/Graphene Nanoplatelets with Enhanced Thermal Properties. 2018 IEEE 9th International Conference on Mechanical and Intelligent Manufacturing Technologies.

P.G. Selingra, C.M., Jaramillo, L. Fama, S. Goyanes, (2016). Biodegradable and Non-Retrogradable Eco-Films Based on Starch-Glycerol with Citric Acid as Crosslinking Agent. Carbohydrate Polymers. 138. 66–74.

R. Chandra, R. Rustgi, (1998). Biodegradable Polymers. Progress in Polymer Science. 23. 1273–1335. R. Shi, Z. Zhang, Q. Liu, Y. Han, (2007). Characterization of Citric Acid/Glycerol Co-Plasticized Thermoplastic Starch Prepared by Melt Blending. Carbohydrate Polymers. 69. 748–755. https://doi.org/10.1016/j.carbpol.2007.02.010

T.M. Ogunrinola, U.G. Akpan, (2018). Production of Cassava Starch Bioplastic Film Reinforced with Poly-Lactic Acid (PLA). International Journal of Engineering Research and Advanced Technology. 4(8). 56–61.

X.F. Ma, J.G. Yu, N. Wang, (2007). Fly Ash-Reinforced Thermoplastic Starch Composites. Carbohydrate Polymers. 67. 32–39. https://doi.org/10.1016/j.carbpol.2006.04.012

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Published

2020-11-30

How to Cite

Kassim Shaari, N. Z., Bairik, M., & Jai, J. (2020). Effect of different loading low density polyethylene (LDPE) on the thermal and mechanical properties of Tapioca starch-based plastic composite. Malaysian Journal of Chemical Engineering &Amp; Technology, 3(1), 25–28. https://doi.org/10.24191/mjcet.v3i1.10928