Formulation of Polymer Composite from Starch/PVA and Crosslinking with Silica from Rice Husk Ash for Polymer Flooding

Authors

  • Muhammad Afiq Iqmal Mohd Yunan Faculty of Chemical Engineering, Universiti Teknologi MARA, 40450 Shah Alam, Selangor, Malaysia
  • Norin Zamiah Kassim Shaari Faculty of Chemical Engineering, Universiti Teknologi MARA, 40450 Shah Alam, Selangor, Malaysia

DOI:

https://doi.org/10.24191/mjcet.v8i2.8543

Keywords:

Polymer composite, Starch, Silica, Rice husk ash, Polymer flooding, Enhanced oil recovery

Abstract

This research project focuses on the creation of a polymer composite by combining potato starch, polyvinyl alcohol (PVA), and silica from rice husk ash (RHA) for polymer flooding in enhanced oil recovery (EOR). This study aims to overcome the limitations of the polymer use for EOR, such as polymer degradation, shear-thinning behaviour, and viscosity control of the polymer. The polymer blend of starch/PVA was crosslinked with silica from RHA, which is expected to enhance the shear-thinning behaviour and control the viscosity of polymer solutions. The investigation involves varying silica concentration to observe its impact on shear rate and viscosity. The methodology includes the extraction of silica from rice husk and the preparation of the polymer composite solution, followed by characterisation of the polymer using Fourier Transform Infrared Analysis and viscosity analysis. The polymer composite was expected to withstand the harsh conditions in the reservoir, which can help to enhance the oil recovery. The polymer composites showed stability in viscosity as the temperature rose, indicating high thermal stability, with no effects from the salinity in 2.5% and 5% saline concentration. In conclusion, the presence of silica, particularly 3%, can improve the rheological properties of biopolymer solutions, making them more stable under reservoir conditions such as high salinity and temperature.

Author Biographies

Muhammad Afiq Iqmal Mohd Yunan, Faculty of Chemical Engineering, Universiti Teknologi MARA, 40450 Shah Alam, Selangor, Malaysia

Muhammad Afiq Iqmal Mohd. Yunan, a graduate with the Bachelor of Engineering (Hons.) Oil and Gas, Faculty of Chemical Engineering, Universiti Teknologi MARA, Shah Alam, Selangor.

Norin Zamiah Kassim Shaari, Faculty of Chemical Engineering, Universiti Teknologi MARA, 40450 Shah Alam, Selangor, Malaysia

Norin Zamiah Kassim Shaari, PhD is an Associate Professor in the Faculty of Chemical Engineering, Universiti Teknologi MARA, Shah Alam, Selangor. Malaysia. She has obtained a Professional Engineer (Ir.) status by the Board of Engineer Malaysia and a Chartered Engineer from the Institution of Chemical Engineers, UK. She is currently the Deputy Dean of Academic Affairs in the faculty. Her research fields are membrane fabrication and separation performance, particularly in the removal of heavy metal ions from water. Other than that, she involves in the fabrication of polymer composite, focusing on the incorporation of silica from rice husk ash as the crosslinker.

References

Abbas, A., Moslemizadeh, A., Sulaiman, W.R., Jaafar, M.Z., & Agi, A. (2020). An insight into di-chain surfactant adsorption onto sandstone minerals under different salinity-temperature conditions: Chemical EOR applications. Chemical Engineering Research and Design, 153, 657–665. https://doi.org/10.1016/j.cherd.2019.11.021

Agi, A., Junin, R., & Gbadamosi, A. (2018). Mechanism governing nanoparticle flow behaviour in porous media: insight for enhanced oil recovery applications. International Nano Letters 8(2), 49–77. https://doi.org/10.1007/s40089- 018-0237-3

Al Soubaihi, R., Saoud, M., Slocombe, M., Al-hussen, K., Al-Muhtaseb, S., & Saoud, K. (2025). Inorganic synthesis of layered mesoporous silica nanosheets and their application in trimethylamine (TMA) sensing. Graphene and 2D Materials. https://doi.org/10.1007/s41127-025-00095-z

Hari Gopi, K., Dhavale, V. M., & Bhat, S. D. (2019). Development of polyvinyl alcohol/chitosan blend anion exchange membrane with mono and di quaternizing agents for application in alkaline polymer electrolyte fuel cells. Materials Science for Energy Technologies 2(2), 194–202. https://doi.org/10.1016/j.mset.2019.01.010

Herrera, M.P., Vasanthan, T., & Chen, L. (2017). Rheology of starch nanoparticles as influenced by particle size, concentration and temperature. Food Hydrocolloids, 66, 237–245. https://doi.org/10.1016/j.foodhyd.2016.11.026

Ji, T., Ma, C., Brisbin, L., Dong, Y., & Zhu, J. (2018). Effect of interface on the mechanical behavior of polybutadiene-silica composites: An experimental and simulation study. Journal of Applied Polymer Science, 135(16), Article 46089. https://doi.org/10.1002/app.46089

Jiang, S., Liu, C., Han, Z., Xiong, L., & Sun, Q. (2016). Evaluation of rheological behavior of starch nanocrystals by acid hydrolysis and starch nanoparticles by self-assembly: a comparative study, Food Hydrocolloids, 52, 914–922. https://doi.org/10.1016/j.foodhyd.2015.09.010

Khan, M.Y., Samanta, A., Ojha, K., & Mandal, A. (2009). Design of alkaline/surfactant/polymer (ASP) slug and its use in enhanced oil recovery. Petroleum Science and Technology, 27(17), 1926–1942. https://doi.org/10.1080/10916460802662765

Leslie, T., Xiao, H., & Dong, M. (2005). Tailor-modified starch/cyclodextrin-based polymers for use in tertiary oil recovery. Journal of Petroleum Science and Engineering, 46, 225–232. https://doi.org/10.1016/j.petrol.2005.01.003

Mudgil, D., Barak, S., & Khatkar, B.S. (2014). Guar gum: processing, properties and food applications—a review. Journal of food science and technology, 51, 409– 418. https://doi.org/10.1007/s13197-011-0522-x

Musa, T.A., Ibrahim, A.F., Nasr-El-Din, H.A., & Hassan, A. (2021). New insights into guar gum as environmentally friendly polymer for enhanced oil recovery in high-salinity and high-temperature sandstone reservoirs. Journal of Petroleum Exploration and Production, 11, 1905–1913. https://doi.org/10.1007/s13202-020-01080-3

Oosten, B.J. (1982). Tentative hypothesis to explain how electrolytes affect the gelatinization temperature of starches in water. Starch, 34, 233–239. https://doi.org/10.1002/star.19820340706

Orodu, K. B., Afolabi, R. O., Oluwasijuwomi, T. D., & Orodu, O. D. (2019). Effect of aluminum oxide nanoparticles on the rheology and stability of a biopolymer for enhanced oil recovery. Journal of Molecular Liquids, 288, Article 110864. https://doi.org/10.1016/j.molliq.2019.04.141

Piana, G., Ricciardi, M., Bella, F., Cucciniello, R., Proto, A., & Gerbaldi, C. (2020). Poly(glycidyl ether)s recycling from industrial waste and feasibility study of reuse as electrolytes in sodium-based batteries. Chemical Engineering Journal, 382, Article 122934. https://doi.org/10.1016/j.cej.2019.122934

Pope, G.A. (2011). Recent Developments and Remaining Challenges of Enhanced Oil Recovery, Journal of Petroleum Technology 63(07), 65–68. https://doi.org/10.2118/0711-0065-JPT

Reddy, B.R. (2011, April). Viscosification-on-demand: chemical modification of biopolymers to control their activation by triggers in aqueous solutions [Paper presentation] SPE International Symposium on Oilfield Chemistry, The Woodlands, Texas, USA. https://doi.org/10.2118/141007-MS

Saboorian-Jooybari, H., Dejam, M., & Chen, Z. (2016). Heavy oil polymer flooding from laboratory core floods to pilot tests and field applications: half-century studies. Journal of Petroleum Science and Engineering, 142, 85–100. https://doi.org/10.1016/j.petrol.2016.01.023

Samanta, A., Ojha, K., & Mandal, A. (2011). The characterization of natural surfactant and polymer and their use in enhanced recovery of oil. Petroleum Science and Technology, 29(7), 765–777. https://doi.org/10.1080/10916460903485819

Shi, A.M., Li, D., Wang, L., & Adhikari, B. (2012). The effect of NaCl on the rheological properties of suspension containing spray dried starch nanoparticles, Carbohydrate Polymers, 90(4), 1530–1537. https://doi.org/10.1016/j.carbpol.2012.07.025

Singh, R., & Mahto, V. (2017). Synthesis, characterization and evaluation of polyacrylamide graft starch/clay nanocomposite hydrogel system for enhanced oil recovery. Petroleum Science, 14(4), 765–779. https://doi.org/10.1007/s12182-017-0185-y

Wagh, P. B., Ingale, S. V., Kumar, R., Patel, R. P., Gupta, S. C., Pisal, A. A., & Rao, A. V. (2015). Comparative Studies of Commercially Available Thermal Insulation Materials and Sol – Gel Processed Thermal Insulation Materials. Journal of Chemical, Biological and Physical Sciences, 5(2), 1944–1949.

Downloads

Published

2025-10-31

How to Cite

Mohd Yunan, M. A. I., & Kassim Shaari, N. Z. (2025). Formulation of Polymer Composite from Starch/PVA and Crosslinking with Silica from Rice Husk Ash for Polymer Flooding. Malaysian Journal of Chemical Engineering and Technology, 8(2), 158–167. https://doi.org/10.24191/mjcet.v8i2.8543